山西大学学报（自然科学版）2012，Vol.35Issue(1)：92-95,4.
1,1'-(1,2-环己基)-3,3＇-烯丙基硫脲的合成和晶体结构研究
Synthesis and Crystal Structure of 1,1'-(cyclohexane-1,2-diyl)bis(3-allylthiourea)
摘要
Abstract
1,1'-(cyclohexane-l,2-diyl)bis(3-allylthiourea) was synthesized by the reactions of 1.2-diamino-cyclohexane with allyl isothiocyanate which was prepared from 3-allyl bromide and potassium thiocyanate. The single crystals suitable for X-ray measurement were obtained by the slow evaporation of the mixed solvent of ethyl acetate and petroleum ether at room temperature. The compound was characterized by 1 H NMR,13C NMR.IR and single crystal X-ray diffraction. The crystal belongs to orthorhombic,space group Pcca.cell parameters a = 21.040 (4),b = 9.680 0(19), c = 17.260 (3) ,α=90°,β=90°,γ=90°.关键词
硫脲类化合物/1,1＇-(1,2-环己基)-3,3＇-烯丙基硫脲/有机合成/晶体结构Key words
thiourea chemical compound/ 1, l'-(cyclohexane-1.2-diyl)bis(3-allylthiourea)/ organic synthesis/ crystal structure分类
化学化工引用本文复制引用
乔秀云,李成义,钞建宾,刘滇生,黄淑萍..1,1'-(1,2-环己基)-3,3＇-烯丙基硫脲的合成和晶体结构研究[J].山西大学学报（自然科学版）,2012,35(1):92-95,4.基金项目
国家自然科学基金(20772074) （20772074）
