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苝四甲酸二酐有机单晶纳米结构的制备及形成机理的研究

韩玉岩 曹亮 徐法强 陈铁锌 郑志远 万力 刘凌云

物理学报2012,Vol.61Issue(7):487-494,8.
物理学报2012,Vol.61Issue(7):487-494,8.

苝四甲酸二酐有机单晶纳米结构的制备及形成机理的研究

Preparation and investigation of the formation mechanism of organic single crystal nanostructures of PTCDA

韩玉岩 1曹亮 1徐法强 1陈铁锌 1郑志远 1万力 1刘凌云1

作者信息

  • 1. 中国科学技术大学国家同步辐射实验室,核科学技术学院,合肥230029
  • 折叠

摘要

Abstract

Different types of nanostructures of an organic dye compound,perylene-3,4,9,10-tetracarboxylic-dianhydride(PTCDA),are prepared on anodic alumina oxide(AAO) at different values of substrate temperature(T_s) by a facile physical vapor deposition(PVD) method in a molecular beam epitaxy(MBE) system.Scanning electron microscopy(SEM),transmission electron microscopy(TEM), high resolution transmission electron microscopy(HRTEM) and selected area electron diffraction(SAED) techniques are applied to the systematical characterization of the nanostructures.It is found that the PTCDA nanofibers,nanoneedles,nanobelts,and nanorods are produced at 330℃T_s;Only nanorods are formed at 280℃,230℃,and 180℃,and their lengths become short as T_s decreases; the continuous films are obtained on 50℃AAOs substrates.HRTEM and SAED results show that the nanoneedle and nanorods are of single crystal.According to SEM results,the formation of PTCDA nanostructures should be mainly affected by surface curvature and

关键词

苝四甲酸二酐/有机单晶/纳米结构/物理气相沉积

Key words

PTCDA/organic single crystal/nanostructures/physical vapor deposition

分类

通用工业技术

引用本文复制引用

韩玉岩,曹亮,徐法强,陈铁锌,郑志远,万力,刘凌云..苝四甲酸二酐有机单晶纳米结构的制备及形成机理的研究[J].物理学报,2012,61(7):487-494,8.

基金项目

国家自然科学基金(批准号:10975138,10775126)资助的课题~~ ()

物理学报

OA北大核心CSCDCSTPCDSCI

1000-3290

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