信阳师范学院学报(自然科学版)2012,Vol.25Issue(2):197-201,5.DOI:10.3969/j.issn.1003-0972.2012.02.015
有机胺存在下烃基卤化锡与巯基乙酸Sn—Ph键断裂反应机理研究
Sn—Ph Cleavage Reaction Mechanism of Alkyl Organotin Halide with Mercaptoacetic Acid in the Presence of Organic Amines
摘要
Abstract
The characteristics of the reaction of alkyl organotin halide with mercaptoacetic acid in the presence of organic amines was studied. The alkyl type and number had a great impact for the structure of the product. A Sn-Ph bond cleavage occurred in the reaction when the three alkyl organotin halide containing phenyl. The mechanism for Sn-Ph bond cleavage was reasoned and verified.关键词
反应机理/离子型有机锡/Sn-Ph键断裂Key words
reaction mechanism / ionic organotin/ Sn-Ph cleavage分类
化学化工引用本文复制引用
钟桂云,孙丽娟..有机胺存在下烃基卤化锡与巯基乙酸Sn—Ph键断裂反应机理研究[J].信阳师范学院学报(自然科学版),2012,25(2):197-201,5.基金项目
国家自然科学基金项目(20372035) (20372035)