地质通报2012，Vol.31Issue(4)：608-613,6.
对电感耦合等离子体质谱法测定的地下水中B元素不确定度的评定
Uncertainty evaluation for determination of boron in groundwater samples by inductively coupled plasma-mass spectrometry
摘要
Abstract
The measurement uncertainty of the analytical results of B in groundwater samples by inductively coupled plasma-mass spectrometry (ICP-MS) was evaluated using continuous propagation model of uncertainty and the regression ofχ, y double error was used in the course of standard curve fitting. The main sources of measurement uncertainty include the sub-uncertainties of standard stock solution, the preparation of the standard series solution, repeated measurements and the fitting of standard curve. Compared with the uncertainty results obtained by the least squares linear fitting, the results obtained by the regression of double error are more accurate for relatively high concentrations.关键词
不确定度/B/地下水/ICP-MS/双误差回归Key words
uncertainty/boron/groundwater/ICP-MS/regression of double error分类
资源环境引用本文复制引用
王亚平,许春雪,代阿芳,王苏明,袁建..对电感耦合等离子体质谱法测定的地下水中B元素不确定度的评定[J].地质通报,2012,31(4):608-613,6.基金项目
国土资源部公益性行业科研专项《矽线石成分标准物质研制》(编号:200911044-02-3) （编号:200911044-02-3）
