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对电感耦合等离子体质谱法测定的地下水中Ag元素不确定度的评定

王亚平 潘河 许春雪 代阿芳 王苏明 袁建

地质通报2012,Vol.31Issue(4):614-618,5.
地质通报2012,Vol.31Issue(4):614-618,5.

对电感耦合等离子体质谱法测定的地下水中Ag元素不确定度的评定

Uncertainty evaluation for the determination of silver in groundwater samples by inductively coupled plasma-mass spectrometry

王亚平 1潘河 2许春雪 1代阿芳 1王苏明 3袁建1

作者信息

  • 1. 国家地质实验测试中心,北京100037
  • 2. 黑龙江省地质矿产测试应用研究所,黑龙江哈尔滨150036
  • 3. 安徽地质实验研究所,安徽合肥230001
  • 折叠

摘要

Abstract

The measurement uncertainty of the analytical results of Ag in groundwater samples by inductively coupled plasma-mass spectrotnetry (ICP-MS) was evaluated using continuous propagation model of uncertainty. The regression of double error was used in the course of standard curve fitting. The extended uncertainty of measurement results was obtained from the synthesis of uncertainties from each source. When the silver content of the actual samples is relatively low, the uncertainty generated in the course of standard curve fitting is comparatively large and even becomes the dominant factor.

关键词

电感耦合等离子体质谱法/地下水/Ag/不确定度/双误差回归

Key words

ICP-MS/groundwater/silver/uncertainty/regression of double error

分类

资源环境

引用本文复制引用

王亚平,潘河,许春雪,代阿芳,王苏明,袁建..对电感耦合等离子体质谱法测定的地下水中Ag元素不确定度的评定[J].地质通报,2012,31(4):614-618,5.

基金项目

国土资源部公益性行业科研专项《矽线石成分标准物质研制》(编号:200911044-02-3) (编号:200911044-02-3)

地质通报

OA北大核心CSCDCSTPCD

1671-2552

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