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PS—EG插层复合物制备及其改性聚苯乙烯的研究

侯桂香 姚少巍 桑晓明 唐鹏 蒋丽

中国塑料Issue(3):88-91,4.
中国塑料Issue(3):88-91,4.

PS—EG插层复合物制备及其改性聚苯乙烯的研究

Preparation of Polystyrene-expanded Graphite Intercalated Complex and Its Modification on Polystyrene

侯桂香 1姚少巍 1桑晓明 1唐鹏 1蒋丽1

作者信息

  • 1. 河北联合大学材料科学与工程学院 河北省无机非金属材料重点实验室,河北唐山063009
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摘要

Abstract

Expandable graphite was prepared from natural flake graphite via chemical oxidation and high temperature processing. Via in-situ polymerization of styrene in presence of expanded graphite polystyrene-expanded graphite (PS-EG) composites were obtained. Melt blending PS-EG with neat polystyrene leaded to polystyrene/polystyrene-expanded (PS/PS-EG) composites. The mechanical properties, thermal stability, and the microstructure of the composites were studied. The impact strength, and thermal stability were improved with the adding of PS-EG. Compared with the neat polystyrene, the impact strength of PS/PS-EG composites was improved 63. 4 %, when the content of PS-EG was 9 %, however the tensile strength showed a large decreasing. Micro-analysis showed that expanded graphite dispersed homogeneously in the form of vermiculate in the composites, and the existence of PS-EG increased the interface effect of PS/PS-EG composite, the cross section of the composites displayed a pinhole structure.

关键词

聚苯乙烯/膨胀石墨/原位聚合/插层/复合材料

Key words

polystyrene/expanded graphite/in situ polymerization/intercalation/composite

分类

化学化工

引用本文复制引用

侯桂香,姚少巍,桑晓明,唐鹏,蒋丽..PS—EG插层复合物制备及其改性聚苯乙烯的研究[J].中国塑料,2012,(3):88-91,4.

中国塑料

OA北大核心CSCDCSTPCD

1001-9278

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