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溴/氮本质阻燃环氧树脂的热性能和阻燃性能研究

贾修伟 楚红英 刘治国

中国塑料Issue(5):88-93,6.
中国塑料Issue(5):88-93,6.

溴/氮本质阻燃环氧树脂的热性能和阻燃性能研究

Study on Thermal and Flame Retardancy of Br/N Intrinsically Flame Retarded Epoxy Resins

贾修伟 1楚红英 2刘治国3

作者信息

  • 1. 河南大学药学院河南省高校无机离子交换树脂工程中心,河南开封475004
  • 2. 黄河水利职业技术学院环境与化学工程系,河南开封475004
  • 3. 西华大学物理与化学学院,四川成都610039
  • 折叠

摘要

Abstract

Flame retardancy, thermal properties, and smoke suppression of epoxy resins treated with poly(N 2,3,5,6-tetrabromo-p-dimethyl phenyl)-ethylamine (BNFR) were investigated by means of thermogravimetric analysis, Fourier transform infrared (FTIR), limited oxygen index, and comprehensive vertical flame detector. It showed that owing to participation in the curing reaction of epoxy compounds and hardeners, BNFR was covalently bonded in the hardened three- dimensional network, the leaching during processing cycle and usage periods was inhibited. BNFR had excellent flame retardant effectiveness. After adding 12 % BNFR, the limited oxygen index of conventional epoxy resins was 30 %, and the char residual ration reached to 10 % at 600 ℃.

关键词

低聚物/环氧树脂/反应型阻燃剂/阻燃性能/热性能

Key words

oligomer/epoxy resin/reactive flame retardant/flame retardancy/thermal property

分类

化学化工

引用本文复制引用

贾修伟,楚红英,刘治国..溴/氮本质阻燃环氧树脂的热性能和阻燃性能研究[J].中国塑料,2012,(5):88-93,6.

中国塑料

OA北大核心CSCDCSTPCD

1001-9278

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