分析测试学报2012，Vol.31Issue(6)：705-709,5.DOI:10.3969/j.issn.1004-4957.2012.06.014
应用热脱附-气相色谱质谱法测定空气中化学毒剂模拟剂
Determination of Chemical Warfare Agents Simulants in Air by Thermal Desorption and Gas Chromatography- Mass Spectrometry
摘要
Abstract
In this paper, Tenax -TA tubes were used for air sampling with a small volume air sampler, and a gas chromatography -mass spectrometer(GC - MS) equipped with thermal desorber was adopted to analyze 4 simulant warfare agents, including 1 , 2-dichloroethane, N, N-dimethylacet-amide, trimethyl phosphate and dimethyl methylphosphonate. The results showed that good lineari-ties for four simulant CWAs were obtained in the range of 1 100 ng/tube with correlation coefficients (r2 ) more than 0. 99. The average spiked recoveries were in the range of 82% - 112% . The limits of detection( LODs) ranged from 0. 13 ng/tube to 0. 26 ng/tube, and the relative standard deviations (RSDs) were less than 15%.关键词
热脱附/气相色谱质谱联用仪/化学毒剂/空气/模拟剂Key words
thermal desorption/ gas chromatography - mass spectrometry ( GC - MS ) / chemical warfare agents (CWAs) / air/ simulants分类
化学化工引用本文复制引用
田福林,李红,刘成雁,王志嘉,任雪冬,吕津毅..应用热脱附-气相色谱质谱法测定空气中化学毒剂模拟剂[J].分析测试学报,2012,31(6):705-709,5.基金项目
辽宁省重点实验室专项资金计划项目(20051043) （20051043）
辽宁省博士科研启动基金资助项目(20101051) （20101051）
