高等学校化学学报2012，Vol.33Issue(5)：876-879,4.DOI:10.3969/j.issn.0251-0790.2012.05.002
[ Co(en)3]2(Zr2F12)(ZrF6H2O)·H2O的合成、结构及表面光电压性质
Synthesis, Structure and Surface Photovoltage Characterization of [ Co (en) 3 ]2 ( Zr2 F12) ( ZrF6 H2O) · H2O
摘要
Abstract
[Co(en)3]2(Zr2F12) (ZrF6H2O)· H2O(1) was prepared successfully at room temperature and structurally characterized by single-crystal X-ray diffraction analysis. Crystal data for compound 1 are as follows; monoclinic, C2/c, α = 3.06110(17) tun, 6 = 0.877680(5) nm, c=1.50811 (9) nm, β = 118.897 , V=3. 547(4) nm3, Z = 8. Compound 1 consists of one binuclear [Zr2F12]4-unit, one mono-nuclear [ZrF6H20]2- unit, one cobalt ammine complex [Co(en)3]3+ unit and one water molecule, among which exist extensive hydrogen bonds. The surface photovoltage spectrum of compound 1 exhibit a signal at 339 run, which is attributed to the cooperative behaviors between cobalt ammine complex and metal fluoride ions through interactions of them.关键词
氟化锆/钴胺配合物/氢键/光电压Key words
Zirconium fluoride/ Cobalt ammine complex/ Hydrogen-bonding/ Photovoltage分类
化学化工引用本文复制引用
韩义德,杜宇,李乙,宋晓伟,于吉红,徐如人..[ Co(en)3]2(Zr2F12)(ZrF6H2O)·H2O的合成、结构及表面光电压性质[J].高等学校化学学报,2012,33(5):876-879,4.基金项目
国家自然科学基金(批准号:21001050)和国家“九七三”计划项目(批准号:2011CB808703)资助. （批准号:21001050）
