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钾掺杂对铈锆固溶体催化性能的影响

王婷婷 谢其刚 洪燕霞 梁红 李树华

Publication timeAuthors Issue 9,2017
Publication timeAuthorsYears:2007-2011,5.

钾掺杂对铈锆固溶体催化性能的影响

Influences of doping potassium on catalytic performances of ceria-zirconia solid solutions

王婷婷 1谢其刚 1洪燕霞 1梁红 1李树华1

作者信息

  • 1. 广州大学化学化工学院,广州510006
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Abstract

A series of xK-Ce0.7Zr0.302(x =0.05, 0. 10, 0. 15, 0.20, 0.25, 0.30) solid solutions were prepared. The influence of doping potassium on the catalytic performance for particle materials (PM) oxidation was investigated by temperature-programmed oxidation reaction (TPO). And all the catalysts were characterized by the techniques of X-ray diffraction, BET surface area, Hz-TPR, and Oz-TPD. The results show that the cata- lytic performance of the catalyst which prepared by sol-gel method is better than by complex-combustion method. The catalytic performances of xK-Ce0.7Zr0.3 02 (0.10 ≤ x ≤0.30 ) catalysts are obviously better than Ce0.7Zr0.3 02, whose ignition temperature and maximum soot oxidation rate temperature are around 315℃ and 375℃ , respectively. After introduction of potassium, all the catalysts form cubic fluorite structure, and their surface areas decrease with the rise of x value.

关键词

铈锆固溶体/金属钾/催化性能/PM/掺杂

Key words

ceria-zireonia solid solutions/potassium/catalytic performance/PM/dope

分类

资源环境

引用本文复制引用

王婷婷,谢其刚,洪燕霞,梁红,李树华..钾掺杂对铈锆固溶体催化性能的影响[J].环境工程学报,2012,6(6):2007-2011,5.

基金项目

广东省自然科学基金资助项目 ()

广东省社会发展科技项目 ()

环境工程学报

OA北大核心CSCDCSTPCD

1673-9108

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