林产化学与工业2012,Vol.32Issue(2):87-91,5.
以松香基季铵盐为模板剂合成介孔γ-Al2O3
Synthesis of Mesoporous γ-Al2O3 Using Rosin-based Quaternary Ammonium Salt as Template Agent
摘要
Abstract
Aluminas with uniform mesoporous structure was synthesized using rosin-based quaternary ammonium salt as a template agent,and its structure was characterized with X-ray diffraction,transmission electron microscopy and N2 adsorption and desorption.The results indicated that the surface area and pore diameter of the mesoporous γ-Al2O3 calcinated at 650℃ were in the range of 194 -213 m2/g and 4.18 -5.18 nm respectively.The content of the rosin-based quaternary ammonium salt had significant influence on the textural properties of mesoporous γ-Al2O3.The addition of suitable amount of rosinbased quaternary ammonium salt endowed mesoporous γ-Al2O3 with large pore diameter and narrow pore distribution.关键词
介孔氧化铝/松香基季铵盐/γ-Al2O3Key words
mesoporous alumina/ rosin-based quaternary ammonium salt/ γ-Al2O3分类
化学化工引用本文复制引用
王鹏,赵振东,毕良武,陈玉湘..以松香基季铵盐为模板剂合成介孔γ-Al2O3[J].林产化学与工业,2012,32(2):87-91,5.基金项目
国家自然科学基金资助项目(30972319) (30972319)