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以松香基季铵盐为模板剂合成介孔γ-Al2O3

王鹏 赵振东 毕良武 陈玉湘

林产化学与工业2012,Vol.32Issue(2):87-91,5.
林产化学与工业2012,Vol.32Issue(2):87-91,5.

以松香基季铵盐为模板剂合成介孔γ-Al2O3

Synthesis of Mesoporous γ-Al2O3 Using Rosin-based Quaternary Ammonium Salt as Template Agent

王鹏 1赵振东 2毕良武 3陈玉湘4

作者信息

  • 1. 中国林业科学研究院 林产化学工业研究所
  • 2. 生物质化学利用国家工程实验室
  • 3. 国家林业局林产化学工程重点开放性实验室
  • 4. 江苏省生物质能源与材料重点实验室,江苏 南京210042
  • 折叠

摘要

Abstract

Aluminas with uniform mesoporous structure was synthesized using rosin-based quaternary ammonium salt as a template agent,and its structure was characterized with X-ray diffraction,transmission electron microscopy and N2 adsorption and desorption.The results indicated that the surface area and pore diameter of the mesoporous γ-Al2O3 calcinated at 650℃ were in the range of 194 -213 m2/g and 4.18 -5.18 nm respectively.The content of the rosin-based quaternary ammonium salt had significant influence on the textural properties of mesoporous γ-Al2O3.The addition of suitable amount of rosinbased quaternary ammonium salt endowed mesoporous γ-Al2O3 with large pore diameter and narrow pore distribution.

关键词

介孔氧化铝/松香基季铵盐/γ-Al2O3

Key words

mesoporous alumina/ rosin-based quaternary ammonium salt/ γ-Al2O3

分类

化学化工

引用本文复制引用

王鹏,赵振东,毕良武,陈玉湘..以松香基季铵盐为模板剂合成介孔γ-Al2O3[J].林产化学与工业,2012,32(2):87-91,5.

基金项目

国家自然科学基金资助项目(30972319) (30972319)

林产化学与工业

OA北大核心CSCDCSTPCD

0253-2417

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