林产化学与工业2012，Vol.32Issue(2)：107-109,3.
催化氢化3-蒈烯合成蒈烷反应的研究
Synthesis of Carane by Catalytic Hydrogenation of 3-Carene
摘要
Abstract
Hydrogenation of 3-carene which is a component of some special turpentine to prepare carane was studied in an autoclave with a mechanical stirrer. The single factor experiment was carried out, while Raney Ni and Pd/C were used under the conditions of catalysts dosage of 4 %-10 % , time 3-12 h, temperature 60-180 ℃ and die hydrogen pressure 3-9 MPa. It resulted in the optimal reaction conditions as 6 % of Raney Ni based on the mass of 3-carene, pressure 9 MPa, temperature 100 ℃ , and time 3 h. At these conditions, the yield of carane reached 96. 7 % with a selectivity of 92. 8 % and a conversion rate of 99. 5% of carene.关键词
3-蒈烯/蒈烷/催化加氢Key words
3-carene/carane/catalytic hydrogenation分类
化学化工引用本文复制引用
何丽芝,赵振东,王婧,李冬梅,陈玉湘,毕良武..催化氢化3-蒈烯合成蒈烷反应的研究[J].林产化学与工业,2012,32(2):107-109,3.基金项目
科技基础性工作专项(2007FY230200) （2007FY230200）
中国林科院林业新技术所基本科研业务费专项资金(CAFINT2009C01) （CAFINT2009C01）
