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木质颗粒活性炭的孔结构对丁烷吸附性能的影响研究

刘晓敏 邓先伦 朱光真 王国栋 许玉

林产化学与工业2012,Vol.32Issue(2):140-144,5.
林产化学与工业2012,Vol.32Issue(2):140-144,5.

木质颗粒活性炭的孔结构对丁烷吸附性能的影响研究

Effects of Pore Structure of Granular Activated Carbon on n-Butane Adsorption

刘晓敏 1邓先伦 2朱光真 3王国栋 4许玉1

作者信息

  • 1. 中国林业科学研究院 林产化学工业研究所
  • 2. 生物质化学利用国家工程实验室
  • 3. 国家林业局 林产化学工程重点开放性实验室
  • 4. 江苏省生物质能源与材料重点实验室,江苏 南京210042
  • 折叠

摘要

Abstract

Five kinds of wood-based granular activated carbons obtained from different raw materials and technologies have been experimentally studied for n-butane adsorption. The results indicate that butane adsorption capacity of activated carbon is strongly influenced by the specific surface area,pore volume and pore size distribution. It is the micropores between 1. 16 nanometer and 2.0 nanometer that play the most important effect on adsorption. To obtain higher butane working capacity,it is important to form the micropores with diameter between 1. 2 nanometer and 4 nanometer and high pore volume. The butane retentivity is significantly effected by the pores between 0. 5 nanometer and 1.0 nanometer. Besides,as for macropore,it plays unappreciable role in the adsorption value,just acting transport for adsorbates.

关键词

活性炭/孔结构/丁烷工作容量/吸附

Key words

activated carbon/pore structure/the butane working capacity/adsorption

分类

化学化工

引用本文复制引用

刘晓敏,邓先伦,朱光真,王国栋,许玉..木质颗粒活性炭的孔结构对丁烷吸附性能的影响研究[J].林产化学与工业,2012,32(2):140-144,5.

基金项目

国家林业局林业公益性行业科研专项(201004051) (201004051)

“十一五”国家科技支撑计划资助(2009BADBIB03) (2009BADBIB03)

中国林科院林业新技术所基本科研业务费专项资金(CAFINT2009K02) (CAFINT2009K02)

林产化学与工业

OA北大核心CSCDCSTPCD

0253-2417

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