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氨化水饱和预处理麦秸厌氧消化产气性能的研究

杨懂艳 李秀金 冯亚君 张亚甜 袁海荣

可再生能源2012,Vol.30Issue(6):97-102,6.
可再生能源2012,Vol.30Issue(6):97-102,6.

氨化水饱和预处理麦秸厌氧消化产气性能的研究

Study on biogas production of anaerobically digested wheat straw by water-saturation ammonia pretreatment

杨懂艳 1李秀金 2冯亚君 1张亚甜 1袁海荣1

作者信息

  • 1. 北京化工大学资源与环境研究中心,北京100029
  • 2. 北京市环境保护监测中心,北京100044
  • 折叠

摘要

Abstract

Aqueous ammonia was used to pretreat wheat straw to investigate the effect of ammonia amount and loading rates on biogas production. Main compositions of untreated and ammonia-pre-treated wheat straw were analyzed. FTIR was also used to compare the structural characterization of wheat straw,lignin,cellulose and hemicellulose. The results showed that ammonification could improve 14%-23%,26%-36% and 31%~45% biogas production per VS unit at three loading rates respectively. 4% water-saturation ammonia -pretreated wheat straw achieved the highest biogas production of 377 mL/g at the loading rate of 65 g/L It also showed that 39%~42% of hemicellulose, 11% ~20% of cellulose was removed through ammonia pretreatment, while lignin was hardly removed. Structural results showed that ammonia pretreatment could broke down the ester linkage of the waxy cuticular layer, the inner structure of cell was changed and surface area was increased. The inner structure of lignin, hydrogen bonds and β-glycosidic linkages in cellulose and hemill-celulose were broken down, resulting in the separation of cellulose form lignin and dissolve of cellulose, hemicellulose could have a strong affinity for water and can be easily degraded. These changes led to an increase of anaerobic digestion efficiency and biogas yield from wheat straw.

关键词

氢化水饱和预处理/麦秸/厌氧消化/产气量/组分/结构

Key words

water-saturated ammonia-pretreatment/ wheat straw/ anaerobic digestion/ biogas production/ composition/ structure

分类

能源科技

引用本文复制引用

杨懂艳,李秀金,冯亚君,张亚甜,袁海荣..氨化水饱和预处理麦秸厌氧消化产气性能的研究[J].可再生能源,2012,30(6):97-102,6.

基金项目

国家科技部中美国际科技合作项目(2011DFA90800). (2011DFA90800)

可再生能源

OA北大核心CSTPCD

1671-5292

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