日用化学工业2012，Vol.42Issue(2)：84-87,100,5.
一种两性葡萄糖胺表面活性剂的合成与性能研究
Synthesis and properties of an amphoteric glucosamine surfactant
摘要
Abstract
Glucosamine hydrochloride ( GAH) was de - acidified by KOH in ethanol solution to obtain glucosamine ( GA) and the GA further reacted with chloroacetic acid to produce 6 — 0 — carboxymethyl glucosamine (CM - GluN). Then an amphoteric glucosamine surfactant (2 - hydroxy - 3 - dodecyl dimethyl quaternary ammonium) propyl -6 - 0 - carboxymethyl glucosamine ( QA - CM - GluN) was prepared by reaction of epoxypropyldodecyldimethyl ammonium chloride (DTGA) with CM - GluN. The structure of QA -CM - GluN was characterized by IR and elementary analysis. The surface activities of QA - CM - GluN measured at 25 ℃ are as follows; critical micelle concentration (cue) 0.001 mol · L-1, surface tension (γcmc ) 25. 87 mN · m-1 .saturated adsorption (Γmax) 3. 78 × 10-10 mol · cm-2, saturation adsorption area (Amin) 0.44 nm2. Emulsifying power and forming power of the product was measured. The product shows good compatibility with dodecyl dimethyl betaine ( BS - 12), Tween 80 and hexadecyltrimethylammonium chloride (1631) respectively and no stratification phenomenon happens.关键词
两性表面活性剂/葡萄糖胺盐酸盐/合成/表面活性Key words
amphoteric surfactant/glucosamine hydrochloride/synthesis/surface activity分类
化学工程引用本文复制引用
范金石,张敏..一种两性葡萄糖胺表面活性剂的合成与性能研究[J].日用化学工业,2012,42(2):84-87,100,5.基金项目
山东省优秀中青年科学家奖励基金资助项目(2007BS02008) （2007BS02008）
