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一种羧酸盐型双子表面活性剂的合成及性能研究

梅平 赖璐 侯聪 郑延成 陈武 艾俊哲 刘华荣

日用化学工业2012,Vol.42Issue(3):175-179,5.
日用化学工业2012,Vol.42Issue(3):175-179,5.

一种羧酸盐型双子表面活性剂的合成及性能研究

Study on synthesis and properties of a kind of carboxylate gemini surfactant

梅平 1赖璐 1侯聪 1郑延成 1陈武 1艾俊哲 1刘华荣1

作者信息

  • 1. 长江大学 化学与环境工程学院,湖北 荆州 434023
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摘要

Abstract

A kind of carboxylate gemini surfactant CGS - 2 was synthesized by using lauryl amine, dibromoethane and succinic anhydride as starting materials. Structure of the synthetic product was characterized by IR,1HNMR and elemental analysis. Surface activity of the CGS -2 product was investigated. Results showed that,under the optimum synthesis conditions,yield of the intermediate achieves 52.4% ,and the yield from the intermediate to the final product CGS - 2 achieves 91. 5%. Critical micelle concentration of the CGS - 2 product solution achieves 2. 23 × 10-5 mol · L-1 .which is lower than that of the conventional surfactants with order of magnitude of 3. Surface tension of the product can be minimized to 29. 49 mN · m-1.

关键词

双子表面活性剂/羧酸盐/合成/表征/性能

Key words

gemini surfactant/carboxylate/synthesis/characterization/property

分类

化学化工

引用本文复制引用

梅平,赖璐,侯聪,郑延成,陈武,艾俊哲,刘华荣..一种羧酸盐型双子表面活性剂的合成及性能研究[J].日用化学工业,2012,42(3):175-179,5.

基金项目

湖北省自然科学基金创新群体资助项目(2010CDA079) (2010CDA079)

湖北省高等学校优秀中青年创新团队计划资助项目(T201003) (T201003)

中国石油科技创新基金资助项目(2011D-5006-0211) (2011D-5006-0211)

日用化学工业

OA北大核心CSCDCSTPCD

1001-1803

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