沈阳大学学报2012，Vol.24Issue(2)：35-39,5.
杯[4]芳烃衍生物的合成及其晶体结构
Syntheses and Crystal Structures of Calix[4]Arenas Derivatives
摘要
Abstract
A novel phenomenon about calix[4]arenes was observed that there were two discrete conformational isomers observed in single crystals of tetra-O-alkylated calix[4]arenes. Four calix[4] arene derivatives （2, 3, 4 and 5 ） were synthesized with 1 as the precursor, and their single crystals were prepared to disclose reasons for this novel phenomenon. It was found that the introduced alkyl groups inhibited the oxygen-through-the-annulus rotation of phenyl rings, and there was enough space for the forth phenyl ring to randomly position in cone conformation or upside down in partial-cone conformation, leading to the coexistence of two discrete conformational isomers in single crystals of calix[4]arenes.关键词
杯[4]芳烃/构象/晶体结构/构象异构体Key words
calix[4]arene conformation crvstal structure conformational isomer分类
化学化工引用本文复制引用
胡晓钧,彭永标,吴昊..杯[4]芳烃衍生物的合成及其晶体结构[J].沈阳大学学报,2012,24(2):35-39,5.基金项目
国家科技支撑计划课题 （）
