石油化工2012，Vol.41Issue(3)：354-363,10.
环己酮氧化制备己内酯的研究进展
Research Progress in Synthesis of Caprolactone by Cyclohexanone Oxidation
摘要
Abstract
Caprolactone(COSC) is a new nontoxic monomer used in synthesis of poly(caprolactone) which is called a green chemical. Synthesis of COSC by oxidation of cyclohexanone was mainly introduced. The oxidation of cyclohexanone with per-carboxylic acid, H2O2 or O2, and the enzyme catalysis method were summarized. For the H2O2 method, the homogeneous catalyst systems were compared with the heterogeneous catalyst systems. The oxidation of cyclohexanone with H2O2 or O2 was safer, more economical and more environmentally friendly than that with percarboxylic acid.关键词
环己酮/己内酯/氧化剂/催化剂Key words
cyclohexanone/ caprolactone/ oxidant/ catalyst分类
化学化工引用本文复制引用
郭明奇,邱仁华,尹双凤..环己酮氧化制备己内酯的研究进展[J].石油化工,2012,41(3):354-363,10.基金项目
国家自然科学基金项目(20873038) （20873038）
湖南省自然科学杰出青年基金项目(10JJ1003) （10JJ1003）
教育部新世纪优秀人才支持计划(NCET-10-0371) （NCET-10-0371）
湖南大学高校基本科研费资助项目. （）
