石油化工2012，Vol.41Issue(4)：401-404,4.
镍钌/黏土催化糖醇混合物氢解制低碳二元醇
Hydrogenolysis of Sugar Alcohol Mixture to Low Carbon Dihydric Alcolols over NiRu/Ciay Catalyst
摘要
Abstract
A NiRu/clay bimetallic catalyst was prepared through a two-step method(wet blending and then precipitation) and was used in the hydrogenolysis of C5 and Ct sugar alcohol mixture to ethylene glycol, propylene glycol and butylene glycol. Compared to Ni/clay catalyst prepared only through the wet blending, the activity of the catalyst prepared through the two-step method was approximate(the conversion of the C5 and C6 sugar alcohol mixture was 91.21%) and the selectivity increased from 38.88% to 74.09%. The catalysts were characterized by means of TEM and XPS. The results indicated that Ru deposited on the Ni/clay catalyst without disrupting Ni2+particles which could increase the selectivity due to synergistic effect between Ru and Ni.关键词
镍钌/黏土催化剂/糖醇混合物/氢解/乙二醇/丙二醇/丁二醇Key words
NiRu/clay catalyst/ sugar alcohol mixture/ hydrogenolysis/ ethylene glycol/propylene glycol/ butylene glycol分类
化学化工引用本文复制引用
陈洁静,孙兆林,宋丽娟,张倩,白钢,姜恒..镍钌/黏土催化糖醇混合物氢解制低碳二元醇[J].石油化工,2012,41(4):401-404,4.基金项目
辽宁省教育厅资助项目(2009S065). （2009S065）
