石油化工2012，Vol.41Issue(4)：438-442,5.
分散聚合法制备乙二醇单苯醚-甲醛酚醛树脂聚合物微球
Preparation of Ethylene Glycol Monophenylether-Formaldehyde Polymer Microspheres via Dispersion Polymerization
摘要
Abstract
Ethylene glycol monophenylether(EGP)-formaldehyde(EGP-FA) polymer microspheres was prepared from ethylene glycol monophenylether and formaldehyde via dispersion polymerization, with polyvinyl alcohol(PVA) as stabilizer and concentrated H2SO4 as catalyst. The effects of PVA dosage, the ratio of formaldehyde to EGP, temperature, concentrated H2SO4 dosage and stirring rate on the particle size, size distribution and yield of EGP-FA polymer microspheres were investigated. Under the optimum conditions: n(formaldehyde) : n(EGP) of 2.00, 4.5%(w)PVA(based on the mass of EGP and formaldehyde), 14.10%(w)H2SO4(based on the mass of EGP and formaldehyde), 70 ℃. and 700 r/min stirring rate, the particle size, size distribution and yield of EGP-FA polymer microspheres were 384.16 urn, 1.216 and 45.8%, respectively.关键词
乙二醇单苯醚/甲醛/聚合物微球/分散聚合/聚乙烯醇Key words
ethylene glycol monophenylether/ formaldehyde/ polymermicrosphere/ dispersion polymerization/ polyvinyl alcohol分类
化学化工引用本文复制引用
王春华,纪春暖,曲荣君,孙昌梅,陈厚,刘希光..分散聚合法制备乙二醇单苯醚-甲醛酚醛树脂聚合物微球[J].石油化工,2012,41(4):438-442,5.基金项目
山东省自然科学基金项目(Y2007B19) （Y2007B19）
鲁东大学科研基金项目(08-CXA001,032912,042920,LY20072902,LY20082902,LZ20082903). （08-CXA001,032912,042920,LY20072902,LY20082902,LZ20082903）
