新型炭材料2012,Vol.27Issue(2):129-134,6.
静电纺丝法制备多孔纳米炭纤维及其电化学性能研究
The electrochemical performance of porous carbon nanofibers produced by electrospinning
摘要
Abstract
Porous carbon nanofibers were prepared by electrospinning of mixed solutions of polyvinylalcohol/ phenol formaldehyde and polyvinylalcohol/phenol formaldehyde/potassium carbonate, followed by stabilization and carbonization. The microstructure of the samples was studied by SEM and N2 adsorption/desorption. The electrochemical performance of these porous carbon nanofibers as electrodes of electrical double layer capacitors was investigated by cyclic voltammetry and constant current charge/discharge cycling. Results showed that the BET surface areas of as-prepared porous carbon nanofibers with and without potassium carbonate were 668 and 564 m2·g-1, and their specific capacitances were 178 and 165 F·g-1 at a current density of 0.2 A·g-1, respectively.关键词
静电纺丝/多孔纳米炭纤维/酚醛树脂/碳酸钾/电化学性能Key words
Electrospinning/ Porous carbon nanofibers/ Phenolic resin/ Potassium carbonate/ Electrochemical performance分类
化学化工引用本文复制引用
刘双,宋燕,马昌,史景利,郭全贵,刘朗..静电纺丝法制备多孔纳米炭纤维及其电化学性能研究[J].新型炭材料,2012,27(2):129-134,6.基金项目
国家自然科学基金(50602046),山西省自然科学基金(2007011075)和中国科学院山西煤炭化学研究所杰出青年人才基金. (50602046)