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静电纺丝法制备多孔纳米炭纤维及其电化学性能研究

刘双 宋燕 马昌 史景利 郭全贵 刘朗

新型炭材料2012,Vol.27Issue(2):129-134,6.
新型炭材料2012,Vol.27Issue(2):129-134,6.

静电纺丝法制备多孔纳米炭纤维及其电化学性能研究

The electrochemical performance of porous carbon nanofibers produced by electrospinning

刘双 1宋燕 2马昌 1史景利 1郭全贵 2刘朗1

作者信息

  • 1. 中国科学院炭材料重点实验室,中国科学院山西煤炭化学研究所,山西太原030001
  • 2. 中国科学院研究生院,北京100049
  • 折叠

摘要

Abstract

Porous carbon nanofibers were prepared by electrospinning of mixed solutions of polyvinylalcohol/ phenol formaldehyde and polyvinylalcohol/phenol formaldehyde/potassium carbonate, followed by stabilization and carbonization. The microstructure of the samples was studied by SEM and N2 adsorption/desorption. The electrochemical performance of these porous carbon nanofibers as electrodes of electrical double layer capacitors was investigated by cyclic voltammetry and constant current charge/discharge cycling. Results showed that the BET surface areas of as-prepared porous carbon nanofibers with and without potassium carbonate were 668 and 564 m2·g-1, and their specific capacitances were 178 and 165 F·g-1 at a current density of 0.2 A·g-1, respectively.

关键词

静电纺丝/多孔纳米炭纤维/酚醛树脂/碳酸钾/电化学性能

Key words

Electrospinning/ Porous carbon nanofibers/ Phenolic resin/ Potassium carbonate/ Electrochemical performance

分类

化学化工

引用本文复制引用

刘双,宋燕,马昌,史景利,郭全贵,刘朗..静电纺丝法制备多孔纳米炭纤维及其电化学性能研究[J].新型炭材料,2012,27(2):129-134,6.

基金项目

国家自然科学基金(50602046),山西省自然科学基金(2007011075)和中国科学院山西煤炭化学研究所杰出青年人才基金. (50602046)

新型炭材料

OA北大核心CSCDCSTPCDSCI

1007-8827

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