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氨气退火对ZnO纳米线阵列光致发光性质的影响

沈临江 王雷 戚志鹏

徐州工程学院学报:自然科学版2012,Vol.27Issue(2):5-9,5.
徐州工程学院学报:自然科学版2012,Vol.27Issue(2):5-9,5.

氨气退火对ZnO纳米线阵列光致发光性质的影响

The Effect of NH3 Anneal on the Photoluminescence Properties of ZnO Nanowires Array

沈临江 1王雷 1戚志鹏1

作者信息

  • 1. 南京工业大学理学院,南京210009
  • 折叠

摘要

Abstract

The ZnO nanowires were prepared on Si (100) substrate by hydrothermal technology. Prior to the growth of nanowires, thin ZnO seed layer was prepared on the surface of Si substrate by coating. Then, oriented ZnO nanowires were grown on the seed layer through hydrothermal method. The ZnO nanowires were annealed in NH3 at different temperatures. The effect of anneal on their photoluminescence (PL) properties were systematically studied. N acceptor-related emissions appeared in low-temperature PL spectra. The ionization energy of N acceptor was determined as 129 meV from free-electron-to-acceptor (FA) transition. In addition, donor-acceptor pair (DAP) emission showed a slight redshift with increasing annealing temperature. An obvious free-exiton (FE) emission was observed in the PL spectra of ZnO nanowires annealed at 700℃. This phenomenon was proved with theory fitting.

关键词

ZnO纳米线/NH3/退火/光致发光

Key words

ZnO nanowire/NH3 anneal/photoluminescence

分类

数理科学

引用本文复制引用

沈临江,王雷,戚志鹏..氨气退火对ZnO纳米线阵列光致发光性质的影响[J].徐州工程学院学报:自然科学版,2012,27(2):5-9,5.

基金项目

基金项目:国家自然科学基金项目 ()

徐州工程学院学报:自然科学版

1674-358X

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