烟草科技Issue(6):41-44,4.
麦芽酚、乙基麦芽酚的配合物合成、表征及其热裂解研究
Studies on Synthesis, Characterization and Pyrolysis of Zinc (Ⅱ)and Calcium (Ⅱ)Complex Compounds of Maltol and Ethyl Maltol
摘要
Abstract
In order to investigate their pyrolytic behavior, four complexes of maltol/ethyl maltol and zinc (H)/ calcium (II)were prepared and characterized by 'H NMR, 13C NMR, UV, IR spectra. The pyrolytic experiments of the complex alone or in cigarettes were conducted by on-line CDS5200 pyrolyser-G.C/MS. The results showed that: 1) the complexation between maltol/ethyl maltol and zinc (II )/calcium (II) occurred obviously; 2) relevant maltol or ethyl maltol ligands released effectively from each pyrolyzed complex at 400℃. in He atmosphere; 3) the similar ligands were also released from the burning cigarette containing respective complex.关键词
麦芽酚/乙基麦芽酚/热裂解/卷烟烟气Key words
Maltol/ Ethyl maltol/ Pyrolysis/ Cigarette smoke分类
化学化工引用本文复制引用
黎艳玲,李亚白,邓昌健,卢红兵,刘金云,杨华武..麦芽酚、乙基麦芽酚的配合物合成、表征及其热裂解研究[J].烟草科技,2012,(6):41-44,4.基金项目
国家烟草专卖局2010年度重点项目“甜香类香料释放控制技术研究”(中烟办[2010]221号). (中烟办[2010]221号)