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麦芽酚、乙基麦芽酚的配合物合成、表征及其热裂解研究

黎艳玲 李亚白 邓昌健 卢红兵 刘金云 杨华武

烟草科技Issue(6):41-44,4.
烟草科技Issue(6):41-44,4.

麦芽酚、乙基麦芽酚的配合物合成、表征及其热裂解研究

Studies on Synthesis, Characterization and Pyrolysis of Zinc (Ⅱ)and Calcium (Ⅱ)Complex Compounds of Maltol and Ethyl Maltol

黎艳玲 1李亚白 1邓昌健 1卢红兵 1刘金云 1杨华武1

作者信息

  • 1. 湖南中烟工业有限责任公司,长沙市劳动中路426号 410007
  • 折叠

摘要

Abstract

In order to investigate their pyrolytic behavior, four complexes of maltol/ethyl maltol and zinc (H)/ calcium (II)were prepared and characterized by 'H NMR, 13C NMR, UV, IR spectra. The pyrolytic experiments of the complex alone or in cigarettes were conducted by on-line CDS5200 pyrolyser-G.C/MS. The results showed that: 1) the complexation between maltol/ethyl maltol and zinc (II )/calcium (II) occurred obviously; 2) relevant maltol or ethyl maltol ligands released effectively from each pyrolyzed complex at 400℃. in He atmosphere; 3) the similar ligands were also released from the burning cigarette containing respective complex.

关键词

麦芽酚/乙基麦芽酚/热裂解/卷烟烟气

Key words

Maltol/ Ethyl maltol/ Pyrolysis/ Cigarette smoke

分类

化学化工

引用本文复制引用

黎艳玲,李亚白,邓昌健,卢红兵,刘金云,杨华武..麦芽酚、乙基麦芽酚的配合物合成、表征及其热裂解研究[J].烟草科技,2012,(6):41-44,4.

基金项目

国家烟草专卖局2010年度重点项目“甜香类香料释放控制技术研究”(中烟办[2010]221号). (中烟办[2010]221号)

烟草科技

OA北大核心CSTPCD

1002-0861

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