岩矿测试2012，Vol.31Issue(3)：419-424,6.
微波消解-直角加速飞行时间电感耦合等离子体质谱法测定烟叶中砷铅镉汞
Determination of As,Pb,Cd and Hg in Tobacco by Orthogonal Acceleration Time-of-Flight Mass Spectrometry with Microwave Digestion
摘要
Abstract
This article introduces the establishment of an ICP-oaTOF-MS (Orthogonal Acceleration Time-of-Flight Mass Spectrometry ) method for the determination of heavy metals, including As, Cd, Hg and Pb, in over 21 kinds of tobacco in a certain province. The samples were digested in a closed-vessel by microwave. Factors affecting the determination were studied in detail, such as sampling quantity, digestion solvent, working parameters for mass spectrometry, calibration curve, detection limit, recovery and precision tests of the method. The optimum conditions for the determination were tested and are discussed in this paper. For all of the analyzed heavy metals, the correlative coefficients of the calibration curves were over 0.9998. The recovery rates were 91.49% - 106. 25% , relative standard deviations (RSD) were lower than 2% and detection limits were 0. 093 —0. 168 μg/L. Under the given analytical conditions, the contents of the four elements of the same cultivars and stalk positions varied significantly among different locations. The contents of As, Pb, Cd and Hg had ranges of 0.503 - 1.737 mg/kg, 1.826 -4.969 mg/kg, 0.656 -2.641 mg/kg and 0.042 -0.584 mg/kg, respectively. The contents of As and Hg have some small differences, however, the contents of Pb and Cd are significantly different. Compared with other methods, this method is simple, fast and accurate with a high sensitivity. Sample contents are preferably measured in the ng/L range. Therefore, this method can be used in heavy metal detection and quality control for tobacco which is significant to be able to determine the condition of abundance or deficiency for tobacco, and identify the quality of cigarette production.关键词
烟叶/重金属元素/微波消解/直角加速飞行时间电感耦合等离子体质谱法Key words
tobacco/ heavy metal elements/ microwave digestion/ Orthogonal Acceleration Time-of-Flight Mass Spectrometry分类
农业科技引用本文复制引用
何杰,曾千春,旦有明,易建华,宋春满,丁元明..微波消解-直角加速飞行时间电感耦合等离子体质谱法测定烟叶中砷铅镉汞[J].岩矿测试,2012,31(3):419-424,6.基金项目
国家质检总局科技计划项目(2009IK179) （2009IK179）
