中国光学2012,Vol.5Issue(3):203-208,6.
利用能量传递实现可调全色单一白光BaMg2Al6Si9O30∶Eu2+,Tb3+,Mn2+荧光粉(特邀)
Color-tunable white-light emitting BaMg2Al6Si9O30:Eu2+,Tb3+,Mn2+ phosphors via energy transfer(Invited)
摘要
Abstract
Single-phase white-light emitting phosphors BaMg2Al6Si9O30∶ Eu2+,Tb3+,Mn2+ are synthesized by solid state reaction.The energy transfers from Eu2+ to Tb3+ and Eu2+ to Mn2+ in BaMg2Al6Si9O30 are demonstrated by fluorescent spectra,energy transfer efficiency and fluorescent life time analysis.The BaMg2Al6Si9O30∶ Eu2+,Tb3+,Mn2+ shows three emitting colors: 450,542 and 610 nm,which are assigned to the contribution from Eu2+,Tb3+ and Mn2+,respectively.By tuning the relative composition of Tb3+/Mn2+,chromaticity coordinates of(0.31,0.30),color rendering index Ra=90 and Correlated Color Temperature(CCT) of 5 374 K can be achieved upon the excitation of UV light.Experimental results indicate that the present phosphor BaMg2Al6Si9O30∶ Eu2+,Tb3+,Mn2+ can serve as potential candidates for light emitting diodes.关键词
白光荧光粉/单一基质/能量传递/白光照明Key words
white-light emitting phosphor/single-phase/energy transfer/white LED分类
信息技术与安全科学引用本文复制引用
张家骅,吕伟,郝振东,张霞,骆永石..利用能量传递实现可调全色单一白光BaMg2Al6Si9O30∶Eu2+,Tb3+,Mn2+荧光粉(特邀)[J].中国光学,2012,5(3):203-208,6.基金项目
国家自然科学基金资助项目 ()
国家科技部资助项目 ()
吉林省科技发展计划资助项目 ()