地质学报2012,Vol.86Issue(5):829-836,8.
白云鄂博原型钡铁钛石晶体化学研究的新进展
Advances in Crystal-Chemistry Study of Type Bafertisite from Bayan Obo, China
摘要
Abstract
Bafertisite is the first new mineral found in the Bayan Obo iron mine, Inner Mongolia, China. To date, it has been over half a century, but the expression concerned with the formula of type befertisite and unit-cell parameters are still controversial, some even very different. This study compiled all the expressions related to the formula. Combined with the structural refinements of type bafertisite and minerals alike conducted home and abroad and the preliminarily-published chemical compositions, we calculated and re-evaluated atoms per formula unit (apfu) using three calculation methods. Based on this research, the crystal chemical formula of type bafertisite was improved tentatively. In addition, the unit-cell parameters are also in dispute. Based on the preliminary refinement to the crystal structure and enlightenment from crystal structure of the same mineral in East Sea, our improvement to the unit-cell parameters of type bafertisite has solid evidence. Therefore, it is necessary to conduct in-depth research on the type bafertisite. One thing is sure that the crystal chemical formula, unit-cell parameters, and crystal structure need to determination, refinement and modification.关键词
钡铁钛石/晶体结构/晶体化学式/晶胞参数Key words
bafertisite/ structural refinement/ crystal chemical formula/ unit-cell parameters引用本文复制引用
沈敢富,李国武,王凯怡,徐金沙..白云鄂博原型钡铁钛石晶体化学研究的新进展[J].地质学报,2012,86(5):829-836,8.基金项目
本文为国家内然科学基金项目(编号40672025)和中国地质调查局地质调查项目(编号1212011120267)联合资助的成果. (编号40672025)