大连工业大学学报2012，Vol.31Issue(4)：254-257,4.
八钼酸季铵盐催化H2O2氧化醇制备醛酮
Oxidation of alcohols to aldehydes or ketones with H2O2 over quaternary ammonium octamolybdate
摘要
Abstract
A quaternary ammonium octamolybdate [n-C16 H33(CH3)2N]4Mo8O26 catalyst was prepared. This catalyst has a good performance in the oxidation of benzyl alcohol to benzaldehyde. The yield 79. 6% of benzaldehyde was obtained at suitable reaction conditions (n(benzyl) alcohol : n(H2O2) = 1 : 1.2, 15% H2O2, 0.05 g of [n-C16H33(CH3)3N]4Mo8O26, 100 ℃, 1.0 h). This catalyst also has good catalytic activity in the oxidation of aliphatic secondary alcohols; octan-2-ol can gave octan-2-one in the yield of 97.3%.关键词
八钼酸季铵盐/氧化/醇/过氧化氢Key words
quaternary ammonium octamolybdate/ oxidation/ alcohol/ hydrogen peroxide分类
化学化工引用本文复制引用
张家荣,李军,王普光,董晓丽,高爽..八钼酸季铵盐催化H2O2氧化醇制备醛酮[J].大连工业大学学报,2012,31(4):254-257,4.基金项目
国家重点基础研究发展计划(973)项目(2009CB623505) （973）
国家自然科学基金资助项目(20643006). （20643006）
