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用非剧毒试剂制备气态放射性甲基碘在碘吸附器检验中的初步应用

孔海霞 杜建兴 丘丹圭 韩丽红 张大勇 俞杰

辐射防护2012,Vol.32Issue(4):222-227,6.
辐射防护2012,Vol.32Issue(4):222-227,6.

用非剧毒试剂制备气态放射性甲基碘在碘吸附器检验中的初步应用

Study on Methyl Iodide Prepared without Acute Toxicant and Its Trial Application in Iodine Adsorber Test

孔海霞 1杜建兴 2丘丹圭 1韩丽红 1张大勇 2俞杰1

作者信息

  • 1. 中国辐射防护研究院,太原030006
  • 2. 大亚湾核电运营管理有限责任公司,广东深圳518124
  • 折叠

摘要

Abstract

This paper studied a method of substitution, which substituted the non-toxic chlorotrimelthylsilane (Me3SiC1) /sodium iodide (NaI) for the acutely toxic dimethyl sulphate (DMS) as a dealkylating agent for the first time to react with phosphate methylesters in preparing the gaseous radioactive methyl iodide. Comparative tests were carried out between substitution method and DMS method to measure respective cleaning efficiencies of iodine absorber both in lab and in the ventilation system of nuclear power plant. The impact of the substitutes on the organic material components of methyl iodide generator was also evaluated. The results showed that the substitution method was comparable to the former DMS method, and the substitutes was also compatible with the generator. Therefore, the substitution method can be preliminary judged applicable to both workshop and in-place tests of iodine adsorber in nuclear power plants.

关键词

硫酸二甲酯/替代方法/放射性甲基碘/碘吸附器/净化系数

Key words

dimethyl sulphate/substitution method/radioactive methyl Iodide/iodine adsorber/cleaning efficiency

分类

生物科学

引用本文复制引用

孔海霞,杜建兴,丘丹圭,韩丽红,张大勇,俞杰..用非剧毒试剂制备气态放射性甲基碘在碘吸附器检验中的初步应用[J].辐射防护,2012,32(4):222-227,6.

辐射防护

OA北大核心CSCDCSTPCD

1000-8187

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