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同步辐射光电离质谱法研究卷烟主流烟气气相成分

王健 翁俊桀 贾良元 潘洋

分析化学2012,Vol.40Issue(7):1048-1052,5.
分析化学2012,Vol.40Issue(7):1048-1052,5.DOI:10.3724/SP.J.1096.2012.10886

同步辐射光电离质谱法研究卷烟主流烟气气相成分

Analysis of Gas Phase Components in Mainstream Cigarette Smoke with Synchrotron Radiation Photoionization Mass Spectrometry

王健 1翁俊桀 2贾良元 2潘洋2

作者信息

  • 1. 上海烟草集团有限责任公司技术中心,上海200082
  • 2. 中国科学技术大学国家同步辐射实验室,合肥230029
  • 折叠

摘要

Abstract

The gas-phase components in the mainstream cigarette smoke have been investigated by synchrotron radiation photoionization mass spectrometry. First, the smoke was trapped by a modified syringe. Photoionization mass spectra for the smoke were obtained directly on-line, without pretreatment and separation. Second, ionization energies (IE) of the components at each m/z were obtained by scanning the photoionization efficiency (PIE) spectra. Possible components could be assigned by comparing the experimental IE with known data. Final, the puff-by-puff behaviors of some components were studied using a commercial smoking machine.

关键词

同步辐射/光电离/质谱/主流烟气/气相成分

Key words

Synchrotron radiation/ Photoionization/ Mass spectrometry/ Mainstream cigarette smoke/ Gas phase components

引用本文复制引用

王健,翁俊桀,贾良元,潘洋..同步辐射光电离质谱法研究卷烟主流烟气气相成分[J].分析化学,2012,40(7):1048-1052,5.

基金项目

本文系烟草行业卷烟烟气重点实验室开放研究基金(No.2010-00539)和国家自然科学基金(No.11175185)资助项目 (No.2010-00539)

分析化学

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