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首页|期刊导航|影像科学与光化学|具有聚集诱导发光性能的乙烯基衍生物的合成及其对DNT的检测

具有聚集诱导发光性能的乙烯基衍生物的合成及其对DNT的检测

冷鸿飞 吴文辉

影像科学与光化学2012,Vol.30Issue(3):182-189,8.
影像科学与光化学2012,Vol.30Issue(3):182-189,8.

具有聚集诱导发光性能的乙烯基衍生物的合成及其对DNT的检测

Synthesis of the Vinyl Derivatives with Aggregation Induced Emission Effect and Their Application to the Detection of DNT

冷鸿飞 1吴文辉1

作者信息

  • 1. 北京理工大学材科学院,北京100081
  • 折叠

摘要

Abstract

Two vinyl derivatives with AIE properties were synthesized by Wittig-Horner reaction. The UV and fluorescence spectroscopy shows that the two compounds have weak Π-Π interactions in the aggregation state. Both of them showed strong enhancement fluorescence luminescence properties in the aggregation state. The distortion of their molecular configuration made the diffusion of DNT vapor molecules to the film easier, so the films have shown higher fluorescence quenching efficiency to DNT, and their fluorescence quenching toward DNT is reversible.

关键词

硝基芳烃/聚集诱导发光/三苯胺/荧光猝灭

Key words

nitroaromatic/ aggregation induced emission/ triphenylamine/ fluorescence quenching

分类

化学化工

引用本文复制引用

冷鸿飞,吴文辉..具有聚集诱导发光性能的乙烯基衍生物的合成及其对DNT的检测[J].影像科学与光化学,2012,30(3):182-189,8.

影像科学与光化学

OA北大核心CSCDCSTPCD

1674-0475

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