林产化学与工业2012，Vol.32Issue(3)：13-18,6.
木质素模型化合物香草醛Mannich反应及其产物化学结构表征
Mannich Reaction of Lignin Model Compound Vanillin and Chemical Structure Characterization of Its Product
摘要
Abstract
Vanillin aminated polyol(VAP) was prepared by vanillin, diethanolamine and paraformaldehyde in 1,4-dioxane by Mannich reaction. The effects of material ratio, reaction temperature, reaction time and solvent dosage on the Mannich reaction were investigated. It was observed the highest conversion rate of diethanolamine was up to 84.92 % by dropping 1,3-oxazolidine which was the reaction product of formaldehyde and diethanolamine at 60℃ for 2 h, into vanillin and reacting at 80 ℃ for 3 h in the molar ratio of n( vanillin) : n( formaldehyde) : n(diethanolamine) as 1 : 1 : 1 in 1,4-dioxane of 100 mL/mol vanillin. The chemical structure of vanillin aminated polyol was characterized by HPLC, LC-MS, FT-IR and 'H NMR, respectively.关键词
木质素模型化合物/香草醛/Mannich反应/胺基多元醇Key words
lignin model compound/vanillin/mannich reaction/aminated polyol分类
化学化工引用本文复制引用
聂明才,孔振武,霍淑平,吴国民,陈健..木质素模型化合物香草醛Mannich反应及其产物化学结构表征[J].林产化学与工业,2012,32(3):13-18,6.基金项目
国家林业局948技术引进项目(2008-4-77) （2008-4-77）
