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几种吡啶类化合物对土壤硝化的抑制作用比较

李兆君 宋阿琳 范分良 梁永超

中国生态农业学报2012,Vol.20Issue(5):561-565,5.
中国生态农业学报2012,Vol.20Issue(5):561-565,5.DOI:10.3724/SP.J.1011.2012.00561

几种吡啶类化合物对土壤硝化的抑制作用比较

Comparative studies on soil nitrification inhibition by pyridine compounds

李兆君 1宋阿琳 1范分良 1梁永超1

作者信息

  • 1. 中国农业科学院农业资源与农业区划研究所 农业部植物营养与肥料重点实验室 北京 100081
  • 折叠

摘要

Abstract

Nitrification inhibition is a well-established fertilizer management that improves fertilizer use efficiency (FUE) in crop production aimed at enhanced profitability, crop quality and healthy environment. As a nitrification inhibitor, pyridine compound has been used for stabilization of fertilizer nitrogen (M) for more than 20 years now. However, pyridine compound represents a broad class of heterocyclic N compounds whose activity as nitrification inhibitors appears to be impacted by Cl and/or trichloromethl substitution on C atoms immediately adjacent to the N ring. In addition, the solubility of pyridine compounds in water is very low; which decreases nitrification inhibitory activity. To prove nitrification inhibitory effects, 2-chloro-6(3-chloromethylthiazole)-sulfate, 2-chloro-6(3-chloromethylthiazole)-chloride, pyridine compounds mixture and pyridine X compounds were investigated for inhibitory effects on nitrification of fluvo-aquic soil, red soil and paddy soil using laboratory microcosm experiments. The results showed that nitrate contents in soils treated with pyridine compounds were significantly lower than those of the control. Nitrification inhibition rate range was 2.91%~91.92%. Inhibitory effect of pyridine compounds on soil nitrification increased before 21 d, after which it decreased, with peak effect on 21s d. Differences were noted among inhibitory effects of different pyridine compounds. The effects of 2-chloro-6(3-chloromethylthiazole)-chloride were much stronger than those of other pyridine compounds. Differences were also noted in inhibitory effects of pyridine compounds on nitrification in fluo-aquic soil, red soil and paddy soil. Inhibitory effects of pyridine compounds in the different soils were in the order of: fluvo-aquic soil > paddy soil > red soil. Based on soil type, pyridine compound inhibition effect on nitrification increased with increasing application rate the compounds.

关键词

吡啶类化合物/黑土/红壤/潮土/硝化抑制作用

Key words

Pyridine compound, Black soil, Red soil, Fluvo-aquic soil, Nitrification inhibition

分类

农业科学

引用本文复制引用

李兆君,宋阿琳,范分良,梁永超..几种吡啶类化合物对土壤硝化的抑制作用比较[J].中国生态农业学报,2012,20(5):561-565,5.

基金项目

浙江省重大科技专项(2008C12045-2)资助 (2008C12045-2)

中国生态农业学报

OA北大核心CSCDCSTPCD

2096-6237

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