云南化工2012，Vol.39Issue(3)：13-15,3.
三碘化铑的新合成方法
A New Synthetic Method of Rhodium Iodide
摘要
Abstract
A new method has been introduced to synthesize rhodium iodide, an important homogenous catalyst for earbonylation of methanol, to overcome shortcomings of the present methods. These shortcomings include low yield, poor quality and unacceptability with respect to industrial manufacturing. The new method involves the direct reaction of RhC13 with HI. The yield is up to 98.5% and Cl-ean be minimized to 50 ppm by optimizing synthetic operations, superior to the reported data.关键词
三碘化铑/合成/收率Key words
rhodium iodide/synthesis/yield分类
化学化工引用本文复制引用
刘桂华,匡飞平,潘再富,余尧,侯文明,沈善问,高金翠,杨军,彭玉玲,杨善晓..三碘化铑的新合成方法[J].云南化工,2012,39(3):13-15,3.基金项目
基金项目：本项目得到国家科技支撑计划课题“铂族金属催化材料产业化技术开发”（2012BAE06808）和国家科研院所技术开发专项课题“羰基合成用新型铑均相催化剂中试制备技术”（2010EG115061）的资助. （）
