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蒸发自组装法制备聚苯乙烯胶体晶体

宋昌平 刘俊康 倪忠斌 陈明清 刘士荣

应用化学2012,Vol.29Issue(6):639-642,4.
应用化学2012,Vol.29Issue(6):639-642,4.DOI:10.3724/SP.J.1095.2012.00329

蒸发自组装法制备聚苯乙烯胶体晶体

Preparation of Self-Assembled Polystyrene Sphereic Colloid Crystals by a Solvent Evaporation Method

宋昌平 1刘俊康 1倪忠斌 1陈明清 1刘士荣1

作者信息

  • 1. 江南大学化学与材料工程学院 无锡214122
  • 折叠

摘要

Abstract

Sub-micrometer monodispersed polystyrene microspheres were synthesized by the emulsion polymerization technique. The three-dimensional ordered polystyrene colloidal crystals were fabricated on the surface of emulsion through a solvent evaporation method. We have fabricated colloidal crystals with the thickness of more than 450 μm by using this method. It was found that the key factor of preparation of colloidal crystal was the evaporation rate. The capillary force was the main driving force for the regular assembling of the colloidal crystal. With the decrease of solvent, the floating capability of microspheres decreased due to the increase of viscosity and caused the increase of defects.

关键词

蒸发自组装/胶体晶体/聚苯乙烯微球/毛细管力

Key words

solvent evaporation method, colloid crystal, polystyrene microspheres, capillary force

分类

化学化工

引用本文复制引用

宋昌平,刘俊康,倪忠斌,陈明清,刘士荣..蒸发自组装法制备聚苯乙烯胶体晶体[J].应用化学,2012,29(6):639-642,4.

基金项目

国家自然科学基金(20876070)资助项目 (20876070)

应用化学

OA北大核心CSCDCSTPCD

1000-0518

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