应用化学2012，Vol.29Issue(6)：643-648,6.DOI:10.3724/SP.J.1095.2012.00271
α(β)-四苯氧基酞菁锌的合成、表征和发光性能
Synthesis, Characterization and Luminescent Properties of α(β)-Tetra-phenoxy Phthalocyaninato Zinc
摘要
Abstract
α(β)-tetra-phenoxy phthalocyaninato zinc complexes have been synthesized via a two-step process using 3 (4)-nitrobenzene-1, 2-diearbonitrile and phenol as precursors. The products were characterized by means of IR spectrum, UV-Vis spectrum, H NMR spectrum, mass spectrum and elemental analysis. The UV-Vis spectra, photoluminescence spectra of spin-coated film and pressed solid pellet were compared. The fluorescences of both compressed and spin-coated samples had red-shifts larger than 161 nm compared to that obtained from solution. In addition, their fluorescence peaks are broader than that in solution. The fluorescence of β-substituted phthalocyanines has a greater red-shift than that of α-substituted phthalocyanines. The two kinds of fabricated devices showed similar electroluminescent spectra around 880 nm.关键词
苯氧基酞菁锌/合成/光致发光/电致发光/红移Key words
phenoxy phthalocyaninato zinc,synthesis,photoluminescence,electroluminescence,red-shift分类
化学化工引用本文复制引用
白青龙,张春花,程传辉,李万程,杜国同..α(β)-四苯氧基酞菁锌的合成、表征和发光性能[J].应用化学,2012,29(6):643-648,6.基金项目
国家自然科学基金(60807009)资助项目 （60807009）
