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间苯二酚对三聚氰胺-甲醛碳气凝胶催化剂的影响

李良伟 陈胜洲 林维明

电池2012,Vol.42Issue(3):129-131,3.
电池2012,Vol.42Issue(3):129-131,3.

间苯二酚对三聚氰胺-甲醛碳气凝胶催化剂的影响

Effect of resorcinol to melamine-formaldehyde aerogel catalyst

李良伟 1陈胜洲 1林维明1

作者信息

  • 1. 广州大学化学化工学院,广东广州510006
  • 折叠

摘要

Abstract

Melaimne-resorcinol-formaldehyde( MR) nitrogen contained carbon aerogeK MR-CA) was prepared through the steps of sol-gel,solvent exchange,freeze-drying and carbonization using melamine,resorcinol and formaldehyde as raw materials. The results of specific surface area and microporous analysis showed that the pore size of MR aerogel was 5 - 40 nm, the average pore size was 15.5 nm.The linear scanning test was taken to the prepared catalysts using rotating disk electrode in O2 saturated 0.5 mol/L H2SO4.When the rotation rate was 1 200 r/min,the oxygen reduction limiting current of MR-CA catalyst was about 4 times higher than melamine-formaldehyde nitrogen contained carbon aerogeK MF-CA) catalyst in the same condition.

关键词

碳气凝胶/冷冻干燥/氧还原反应/质子交换膜燃料电池(PEMFC)

Key words

carbon aerogel/ freeze-drying/ oxygen reduction reaction/ proton exchange membrane fuel cell(PEMFC)

分类

信息技术与安全科学

引用本文复制引用

李良伟,陈胜洲,林维明..间苯二酚对三聚氰胺-甲醛碳气凝胶催化剂的影响[J].电池,2012,42(3):129-131,3.

基金项目

国家自然科学基金(21076048),广东省科技厅计划项目(2009B011000022),广州市科技计划项目(2009J1-C-431-1) (21076048)

电池

OA北大核心CSCDCSTPCD

1001-1579

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