电化学2012，Vol.18Issue(4)：291-294,4.
NaF—M（M=Fe，Cu）钠离子电池转换正极材料的研究
NaF-M （M = Fe, Cu） Nanocomposites as Conversion Cathode Materials for Sodium Ion Batteries
摘要
Abstract
NaF-M （M=Fe, Cu） nanocomposites were prepared by high-energy ball milling using TiN grind- ing nanoparticles and investigated as cathode materials for sodium ion batteries. The experimental results dem-onstrated that NaF-Fe and NaF-Cu nanocomposites can go through electrochemical conversion reaction with Na ^＋ uptake or removal, delivering a reversible capacity of- 150 mAh·g^-1, even through a reversed conver-sion from initial discharged state to a charged state. These results reveal the possibility to realize a conversion reaction as long as NaF and elemental metal particles are intimately contacted to form active nanocomposites at nanodomain, which suggests a potential feasibility to use these nanocomposites as sodium-rich cathode materi-als for sodium ion batteries.关键词
电化学转换反应/钠离子电池/正极材料Key words
electrochemical conversion reaction/sodium ion batteries/cathode material分类
化学化工引用本文复制引用
李婷,陈重学,曹余良,杨汉西..NaF—M（M=Fe，Cu）钠离子电池转换正极材料的研究[J].电化学,2012,18(4):291-294,4.基金项目
国家自然科学基金项目（No.2009CB2201003）资助 （）
