高等学校化学学报2012，Vol.33Issue(7)：1466-1470,5.DOI:10.3969/j.issn.0251-0790.2012.07.018
溴代1,4,5,8-萘四甲酸酐的选择性合成
Selective Synthesis of Bromo-substituted Naphthalene Dianhydride Derivatives
摘要
Abstract
In recent years, core-substituted 1,4,5,8-naphthalene diimides (cNDIs) have been widely used in numerous research fields, such as materials and supramolecular chemistry. As the important precursors for the synthesis of cNDIs, 2-bromo and 2,6-dibromo-l ,4,5 ,8-naphthalene dianhydride derivatives are difficult to separate from each other, but their mixture is easily obtained according to the most synthesis conditions which have been reported. In order to develop an efficient, practical method to obtain 2-bromo and 2,6-dibromo-1,4,5,8-naphthalene dianhydride derivatives respectively, the reaction were performed with NaBr and oleum as the bromide reagents under atmospheric pressure, and the effects of reaction time, temperature, S03 content in oleum and NaBr quantity were investigated. 2-Bromo and 2,6-dibromo-l ,4,5,8-naphthalene dianhydride derivatives were selectively synthesized. Their structures and yields were characterized by derivatiza-tion of them for their napnthalimide compounds.关键词
1,4,5,8-萘四甲酸酐(NDA)/溴化钠/选择性合成Key words
Naphthalene dianhydride/ Sodium bromide/ Selective synthesis分类
化学化工引用本文复制引用
张平竹,魏超,段晓旭,张晓媛,王克让,陈华,李小六..溴代1,4,5,8-萘四甲酸酐的选择性合成[J].高等学校化学学报,2012,33(7):1466-1470,5.基金项目
国家"九七三"计划前期研究专项基金(批准号:2010CB534913)、国家自然科学基金(批准号:21172051,21002020)、河北省自然科学基金(批准号:B2011201052)、河北省教育厅基金(批准号:2010106,2009309)和河北大学自然科学研究计划(批准号:2009-175)资助. （批准号:2010CB534913）
