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双酚A环氧树脂改性二氧化双环戊二烯体系固化动力学分析及其性能研究

吕文丽 肖加余 徐旺生 曾竟成 刘钧 蒋卫和

国防科技大学学报2012,Vol.34Issue(3):38-43,62,7.
国防科技大学学报2012,Vol.34Issue(3):38-43,62,7.

双酚A环氧树脂改性二氧化双环戊二烯体系固化动力学分析及其性能研究

Curing dynamics analysis and properties of acycloaliphatic modified by bisphenol A(E- 51) epoxy resin

吕文丽 1肖加余 2徐旺生 1曾竟成 2刘钧 1蒋卫和1

作者信息

  • 1. 国防科技大学航天与材料工程学院,湖南长沙410073
  • 2. 武汉工程大学化工与制药学院,湖北武汉430073
  • 折叠

摘要

Abstract

Acycloaliphatic(CDR -0122) epoxy resin has good heat-resistance, but it is characterized by being brittle. CDR -0122 modified with different mass fraction of epoxy ( E -51) were studied. First, DSC analysis was carried out to determine the activation energy, reaction order and the best curing procedure of the modified resin. Then mechanical property and heat-resistance property of the cured modified resin were tested. The results showed that, compared with the unmodified CDR -0122, the activation energy of the modified resin system decreased slightly, and its tensile strength and flexural strength increased by 52. 38% and 54. 77% , respectively, but the glass transition temperature decreased slightly. Considering all aspects of performance, the system of CDR -0122 modified with 30 wt% E -51 is the best one.

关键词

二氧化双环戊二烯/E-51/改性/力学性能/耐温性能

Key words

acycloaliphatic/ epoxy/ modification/ mechanics property/ heat-resistance

分类

信息技术与安全科学

引用本文复制引用

吕文丽,肖加余,徐旺生,曾竟成,刘钧,蒋卫和..双酚A环氧树脂改性二氧化双环戊二烯体系固化动力学分析及其性能研究[J].国防科技大学学报,2012,34(3):38-43,62,7.

基金项目

国家部委基金项目 ()

国防科技大学学报

OA北大核心CSCDCSTPCD

1001-2486

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