化工进展2012，Vol.31Issue(8)：1816-1819,4.
离子液体-铝盐催化蔗糖制乙酰丙酸甲酯
Investigation on aluminum salt/1,3-dialkyl imidazolium salt catalyzed conversion of sucrose to methyl levulinate
摘要
Abstract
Investigation shows that aluminum salts and their combinations with 1,3-dialkylimmidazolium salts are efficient catalysts for the conversion of sucrose to methyl levulinate in methanol.Especially,the combinations of aluminum salts with 1,3-dimethylimidazolium hydrogen sulfate have high activity for the methyl levulinate synthesis from sucrose and high methyl levulinate yield was obtained.The investigation examined the co-catalysis of aluminum salts and 1,3-dimethylimidazolium hydrogen sulfate.The effects of reaction time,reaction temperature,and catalyst loading on methyl levulinate yield were studied.The reaction conditions were optimized.It was found that good yield（70% in mol） of methyl levulinate could be obtained at 140℃ by reaction 3 h with 1,3-dimethylimidazolium hydrogen sulfate and Al（CH3SO3）3 loading of 0.500 g and 0.500 g,respectively.关键词
蔗糖/乙酰丙酸甲酯/铝盐/离子液体/催化剂Key words
sucrose/methyl levulinate/aluminum salts/ionic liquid/catalyst分类
化学化工引用本文复制引用
茅花,黄和..离子液体-铝盐催化蔗糖制乙酰丙酸甲酯[J].化工进展,2012,31(8):1816-1819,4.基金项目
科技部支持项目 （）
