化工学报2012，Vol.63Issue(8)：2327-2340,14.DOI:10.3969/j.issn.0438-1157.2012.08.001
3-庚酮+乙酸乙酯、3-庚酮+乙酸丁酯、3-庚酮+TBP、MIBK+ TBP二元体系的过量摩尔体积和黏度
Excess molar volumes and viscosities for binary mixtures of 3-heptanone + ethyl acetate, 3-heptanone + butyl acetate, 3-heptanone + tributyl phosphate,and methyl isobutyl ketone + tributyl phosphate
摘要
Abstract
Densities and viscosities of four binary mixtures of 3-heptanone + ethyl acetate, 3-heptanone + butyl acetate, 3-heptanone + tributyl phosphate and methyl isobutyl ketone + tributyl phosphate were determined from 293. 15 K to 318. 15 K under atmospheric pressure using Anton Paar DMA5000 vibrating-tube densimeter and Anton Paar AMVn automated micro viscometer. From the experimental data of density and viscosity, the excess molar volumes VE and viscosity deviation △η were calculated and correlated with the Redlich-Kister polynomial equation. The viscosities of the mixtures were correlated by Orrick-Erbar (OE) group-contribution method. And the new group-contribution parameters A and B for (-O)3-P=O group were obtained. The results show that the improved Orrick-Erbar equation is able to predict the viscosities for mixtures from their pure solvents and the deviation is acceptable in engineering applications.关键词
3-庚酮/磷酸三丁酯/4-甲基-2-戊酮/乙酸乙酯/乙酸丁酯/密度/黏度/Orrick-Erbar (O-E)基团贡献法Key words
3-heptanone/ tributyl phosphate/ methyl isobutyl ketone/ ethyl acetate/ butyl acetate/ density/ viscosity/ Orrick-Erbar group-contribution method分类
化学化工引用本文复制引用
杨得岭,林晓,曹宏斌,李以圭,张懿..3-庚酮+乙酸乙酯、3-庚酮+乙酸丁酯、3-庚酮+TBP、MIBK+ TBP二元体系的过量摩尔体积和黏度[J].化工学报,2012,63(8):2327-2340,14.基金项目
国家自然科学基金项目(51178446) （51178446）
国家高技术研究发展计划项目(2009AA06Z314). （2009AA06Z314）
