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光催化降解水体异味物质2-MIB的机理

何燕 刘立明 张钰 方艳芬 顾彦 黄应平 张爱清

环境工程学报2012,Vol.6Issue(8):2533-2538,6.
环境工程学报2012,Vol.6Issue(8):2533-2538,6.

光催化降解水体异味物质2-MIB的机理

Mechanism for photocatalytic degradation of odor 2-methylisoborneol in drinking water

何燕 1刘立明 1张钰 1方艳芬 1顾彦 1黄应平 1张爱清2

作者信息

  • 1. 三峡库区生态环境教育部工程研究中心三峡大学,宜昌443002
  • 2. 中南民族大学催化材料科学湖北省暨国家民委一教育部共建重点实验室,武汉430074
  • 折叠

摘要

Abstract

The photocatalytic degradation characteristics and photochemical mechanism of odor 2-methyli- soborueol (2-MIB) by TiO2 (P25) under UV irradiation (A 〈 380 nm) were studied. The results showed that 2- MIB in water bodies was effectively degraded in the photocatalytie system of UV/TiO2. The degradation rate of 2- MIB reached 95% under UV illumination for 60 rain. The effects of pH, coexisting humic acid (HA) and potas- sium sulfate (K2S208) on UV/TiO2system were researched. The results demonstrated that low concentration of HA ( ~ O. 5 rag/L) improved the degradation while high concentration of HA ( 〉0.5 rag/L) inhibited the deg- radation of 2-MIB. K2S208, an electronic aceeptor, enhanced the degradation rate of 2-MIB by significantly in- creasing the concentration of hydroxyl radical ( OH) in the system. The concentration of OH and hydrogen peroxide (H202) was determined by the fluorescence method and the N, N-diethyl-p-phenylenediamine (DPD) method.

关键词

2-甲基异莰醇(2-MIB)/TiO2/光催化

Key words

2-methylisoborneol/Ti02/photocatalysis

分类

资源环境

引用本文复制引用

何燕,刘立明,张钰,方艳芬,顾彦,黄应平,张爱清..光催化降解水体异味物质2-MIB的机理[J].环境工程学报,2012,6(8):2533-2538,6.

基金项目

国家自然科学基金资助项目 ()

湖北省创新群体项目 ()

催化材料科学湖北省暨国家民委-教育部共建重点实验室开放基金 ()

环境工程学报

OA北大核心CSCDCSTPCD

1673-9108

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