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电催化氧化法处理染料废水的影响因素及动力学

王开红 岳琳 郭建博

环境工程学报2012,Vol.6Issue(8):2640-2644,5.
环境工程学报2012,Vol.6Issue(8):2640-2644,5.

电催化氧化法处理染料废水的影响因素及动力学

Affecting factors and kinetics of dye wastewater treatment by electro-catalytic oxidation process

王开红 1岳琳 1郭建博1

作者信息

  • 1. 河北科技大学环境科学与工程学院,石家庄050018
  • 折叠

摘要

Abstract

Under the condition of the coating of titanium plate as anode, graphite plate as cathode and Fe203/y-Al2O3 as heterogeneous catalyst, COD removal effect and its affecting factors in dye-wastewater of acid red by electro-heterogeneous catalytic oxidation system were investigated. Experimental conditions and the degra- dation mechanism of COD were discussed. The result shows that cell voltage, pH, airflow rate and electrode dis- tance had a significant impact on COD removal. The best COD removal was 64.5% with cell voltage of 20 V, pH of 4, airflow rate of 0.24 m3/h and electrode distance of 3 cm. The degradation of COD approximation order kinetics equation: In(C0/C) =0. 0034t + 0. 719. It is capable of mineralizing organic contaminants into H2O, CO2 and other inorganics in the electro-heterogeneous catalytic oxidation system.

关键词

电-多相催化氧化/废水处理/酸性大红/COD/动力学

Key words

electro-heterogeneous catalytic oxidation/wastewater treatment/Acid Red/COD/dynamics

分类

资源环境

引用本文复制引用

王开红,岳琳,郭建博..电催化氧化法处理染料废水的影响因素及动力学[J].环境工程学报,2012,6(8):2640-2644,5.

基金项目

河北省科技支撑计划 ()

河北省高等学校科学研究计划 ()

环境工程学报

OA北大核心CSCDCSTPCD

1673-9108

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