含能材料2012,Vol.20Issue(4):385-390,6.DOI:10.3969/j.issn.1006-9941.2012.04.001
呋咱醚含能化合物研究进展
Review on Energetic Compounds Based on Furoxanyl Ether
摘要
Abstract
Energetic compouds based on furoxan ether were a type of important energetic materials with lower melting point, good energy and excellent plasticity. Since 1990s, the type of energetic compounds has been an important research direction in the synthetic fields of energetic materials. In this paper, the synthetic methods of symmetrical and unsymmetrical energetic compouds based on furoxan ether were reviewed. Some representative energetic compounds, such as FOF-1 , FOF-2, FOF-11 and FOF-13, were reviewed, and their syntheses, performances and application were introduced in detail. The structures of 11 novel energetic compouds based on furoxan ether were designed, and their physico-chemical properties, detonating performance were calculated by MP3 semi-empirical method, and the results show that calculated densities of two designed compounds exceed 1.90 g ·cm-3, and theoretical detonation velocities are more than 9000 m ·s-1.关键词
有机化学/综述/呋咱醚含能化合物/合成/性能/研究进展Key words
organic chemistry/ furoxanyl ether/ energetic compounds/ synthesis/ review分类
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王伯周,李辉,李亚南,廉鹏,周彦水,王锡杰..呋咱醚含能化合物研究进展[J].含能材料,2012,20(4):385-390,6.基金项目
国防科研基础计划项目(No.B09201100051) (No.B09201100051)