火炸药学报2012，Vol.35Issue(3)：18-22,5.
3,4-二(4'-氨基-3',5'-二硝基苯基)氧化呋咱的合成及热性能
Synthesis and Thermal Performance of 3,4-Bis (4'-amino-3',5'-dimtrobenzene-1'-yl) furoxan
摘要
Abstract
3,4-Bis(4'-amino-3',5'-dinitrobenzene-l'-yl) furoxan was synthesized from 4-methoxybenzonitrile by six step reactions of oxime"diazotization。Denitrification, cyclization,nitration and amination. The reaction conditions of oxime, cyclization and nitration were optimized and the thermal performance of the title compound was investigated by differential scanning calorimetry(DSC) and thermogravimetry(TG). The results show that the optimum conditions of cyclization with yield of 58. 1% and purity of 99.0％(HPLC) are that the amount of Na2CO3 is 1. 35 times the calculation amount, reaction temperature 2～10℃, reaction time 5 h. The aryl substitutional furoxano compounds has good thermal stability.关键词
有机化学/3,4-二(4'-氨基-3',5'-二硝基苯基)氧化呋咱/合成/热性能Key words
organic chemistry/ 3, 4-bis(4'-amino-3', 5'dinitrobenzene-l'-yl) furoxan/ synthesis/ thermal performance分类
军事科技引用本文复制引用
李亚南,张志忠,廉鹏,王伯周,杨威,王友兵,李辉..3,4-二(4'-氨基-3',5'-二硝基苯基)氧化呋咱的合成及热性能[J].火炸药学报,2012,35(3):18-22,5.基金项目
国防基础产品创新计划科研(No.2371000415)和国防科研基础计划项目(B09201100051)资助. （No.2371000415）
