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金华城区土壤中7种指示性多氯联苯(PCBs)的分布特征和来源分析

王祥云 邓勋飞 杨洪达 徐浩 章虎 李振 齐沛沛 王新全

农业环境科学学报2012,Vol.31Issue(8):1512-1518,7.
农业环境科学学报2012,Vol.31Issue(8):1512-1518,7.

金华城区土壤中7种指示性多氯联苯(PCBs)的分布特征和来源分析

The Distribution and Source Analysis of the Seven Indicator Polychlorinated Biphenyls(PCBs) in Urban Soils of Jinhua City, China

王祥云 1邓勋飞 2杨洪达 3徐浩 1章虎 1李振 1齐沛沛 1王新全1

作者信息

  • 1. 浙江省农业科学院农产品质量标准研究所,农业部农药残留检测重点实验室,省部共建国家重点实验室培育基地“浙江省植物有害生物防控重点实验室” 杭州 310021
  • 2. 浙江省农业科学院数字农业研究所,杭州310021
  • 3. 东北农业大学农学院,哈尔滨150030
  • 折叠

摘要

Abstract

A total of 20 surface(0-20 cm ) soil samples covering the whole urban areas of Jinhua were collected to analyze the seven indicators of PCB congeners (PCB28, PCB52, PCB101, PCB118, PCB138, PCB153, PCB180). The PCB residues concentration ranging from 0.111 μg·kg‐1 to 2.688 μg·kg‐1(dry weight), determined by a gas chromatography tandem mass spectrometry, was lower than that of the most of the cities around the world. Compared to the other cities in China, the PCB homologue composition and the distribution herein were similar. The results that tri- and tetra-PCBs were the main compositions of detected PCBs indicating the source of residues was #1 PCB which used to be popularly produced and used in the country. However, there were also some evidences of the pollution of #2 PCB or imported PCBs. The median concentrations of PCBs in samples from industry regions were obviously higher that of farmlands and parks. Combined the result of principal component analysis that 12 samples from three different functional regions assemble together suggested that the source of PCBs was the industry regions, and air transport might be the main way to dissipation over the city. It was also observed that the concentrations of PCBs in soil samples from farmlands were higher than that from parks, and it might be result from the difference of plants which could also adsorb the pollutions such as PCBs on the land that the plants on the farmlands will be harvested sometime and left the soil exposed in air, while the vegetation in parks always protect the soil from the direct air pollution.

关键词

多氯联苯/金华/城区土壤

Key words

polychlorinated biphenyls/ Jinhua/ urban soil

分类

资源环境

引用本文复制引用

王祥云,邓勋飞,杨洪达,徐浩,章虎,李振,齐沛沛,王新全..金华城区土壤中7种指示性多氯联苯(PCBs)的分布特征和来源分析[J].农业环境科学学报,2012,31(8):1512-1518,7.

基金项目

国家自然科学基金(20807038) (20807038)

浙江省农业科学院科技创新能力提升工程项目 ()

农业环境科学学报

OA北大核心CSCDCSTPCD

1672-2043

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