人工晶体学报2012，Vol.41Issue(2)：461-467,7.
多晶形γ-CuI晶体的制备与导电性能表征
Preparation and Conductivity Characterization of γ-CuI Crystal with Different Morphologies
摘要
Abstract
The γ-CuI crystals with different morphologies were prepared using crude iodine and CuSO4 as raw material, N2H4 ·H2O as reducing agent by liquid phase method and micro-emulsion technique respectively. The effect of liquid phase method and micro-emulsion technique conditions on the microstructure of γ-CuI crystals were studied by XRD and SEM techniques, and the influence of different morphologies on the conductivity of γ-CuI crystal was also analyzed. The results indicated that γ-CuI crystals with nano spherical and triangular pyramidal shapes were prepared respectively by using the liquid phase method, at 500 r/min for 30 min, PEG-6000 and citric acid as surfactants respectively. The γ-Cul crystal with hexagon shape was synthesized from the CuSO4 and NH4I solution prepared by controlling the CTAB: n-pentanol: cyclohexane: water (volume ratio) of 3:3:7:10 respectively, at 500 r/min for 2 h. Different morphologies and crystal sizes had great impact on the conductivity of γ-CuI, and the γ-CuI crystal with nano spherical shape has the lowest conductivity of 4. 9 Ω·cm.关键词
γ-CuI晶体/电导率/液相法/微乳液法Key words
γ-CuI crystal/conductivity/liquid phase method/micro-emulsion technique分类
通用工业技术引用本文复制引用
刘飞,祝博,王晓丹,曹建新..多晶形γ-CuI晶体的制备与导电性能表征[J].人工晶体学报,2012,41(2):461-467,7.基金项目
贵州省科学技术基金项目(黔科合J字[2011]2017) （黔科合J字[2011]2017）
贵州大学博士启动基金项目(2010-014) （2010-014）
贵州省绿色化工创新人才团队项目 （）
贵州瓮福集团产学研合作项目 （）
