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煤直接液化残渣及其萃取产物的热重分析

刘朋飞 张永奇 房倚天

燃料化学学报2012,Vol.40Issue(6):655-659,5.
燃料化学学报2012,Vol.40Issue(6):655-659,5.

煤直接液化残渣及其萃取产物的热重分析

TG analysis of coal direct liquefaction residue and its solvent extracts

刘朋飞 1张永奇 2房倚天1

作者信息

  • 1. 中国科学院山西煤炭化学研究所,山西太原030001
  • 2. 中国科学院研究生院,北京100049
  • 折叠

摘要

Abstract

Pyrolysis of two typical Chinese coal liquefaction residues (Shenhua and Shengli) and their solvent extracts was carried out by TG. The results show that Shenhua and Shengli residue contain similar content of light component, and their weight losses in TGA are similar. However, the different composition of light component in the two residues leads to their difference in TG curves. As increasing of heating rate, the maximum weight loss rate and its corresponding temperature increase. The calculated weight loss calculated from the constitutes is approximately the actual value of the residue. From the kinetic analysis, it is found that the weight loss calculated by the experimental E and k0 agree well with that obtained from the experiment. The weight loss is mainly caused by evaporation of volatile matter which can be extracted by solvent.

关键词

煤直接液化/残渣/热重/萃取/活化能/指前因子

Key words

coal direct liquefaction/ residue/ thermogravimetric analysis/ extract/ activation energy/ frequency factor

分类

化学

引用本文复制引用

刘朋飞,张永奇,房倚天..煤直接液化残渣及其萃取产物的热重分析[J].燃料化学学报,2012,40(6):655-659,5.

燃料化学学报

OA北大核心CSCDCSTPCD

2097-213X

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