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滑动弧放电等离子体分解甲醇制氢

吕一军 闫文娟 胡爽慧 王保伟

燃料化学学报2012,Vol.40Issue(6):698-706,9.
燃料化学学报2012,Vol.40Issue(6):698-706,9.

滑动弧放电等离子体分解甲醇制氢

Hydrogen production by methanol decomposition using gliding arc gas discharge

吕一军 1闫文娟 1胡爽慧 1王保伟1

作者信息

  • 1. 天津大学化工学院绿色合成与转化教育部重点实验室,天津300072
  • 折叠

摘要

Abstract

Direct decomposition of methanol has been investigated using gliding arc gas discharge (GRD) at atmospheric pressure.Depending on the experimental conditions of Ar flow rate,methanol concentration,the electrode gap,input voltage and vaporization room temperature (VRT),different conversions are achieved ranging from 51.0% to 81.7%.Interestingly,the selectivity to the production of hydrogen and carbon monoxide is kept almost constant under all the experimental conditions.The formation of little methane and C2Hx as a byproduct,and trace quantity of carbon dioxide are detected.The reaction channels of methanol decomposition induced by GRD plasma is proposed in detail.

关键词

制氢/甲醇/滑动弧放电

Key words

hydrogen/ methanol/ gliding arc discharge

分类

化学工程

引用本文复制引用

吕一军,闫文娟,胡爽慧,王保伟..滑动弧放电等离子体分解甲醇制氢[J].燃料化学学报,2012,40(6):698-706,9.

基金项目

National Natural Science Foundation of China (21176175,20606023). (21176175,20606023)

燃料化学学报

OA北大核心CSCDCSTPCD

2097-213X

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