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羧甲基纤维素/蜜胺树脂相变纳米储能材料的制备与表征

胡晓峰 黄占华

森林工程2012,Vol.28Issue(4):61-64,76,5.
森林工程2012,Vol.28Issue(4):61-64,76,5.

羧甲基纤维素/蜜胺树脂相变纳米储能材料的制备与表征

Preparation and Characterization of CMC/Melamine Resin Nano-encapsulated Phase Change Energy Storage Materials

胡晓峰 1黄占华1

作者信息

  • 1. 东北林业大学生物质材料科学与技术教育部重点实验室,哈尔滨150040
  • 折叠

摘要

Abstract

Nanocapsulated phase change materials were prepared by in-situ polymerization, using melamine-formaldehyde resin modified by carboxymethyl cellulose (CMC) as the shell and phase change material paraffin as the core. The properties of the products were studied by FTIR, SEM, DSC, and optic microscope, and the influences of the emulsifier sort and stirring rate of paraffin emul- sion preparation on the preparation process of phase change capsules were investigated. The results showed that the phase change cap- sules prepared with anionic emulsifier and nonionic emulsifier are superior to those prepared with simple emulsifier. The performance of paraffin emulsion is optimal when the stirring rate is 8000 r/min in the preparation process of paraffin emulsion. The phase enthalpy of the phase change nano-capsules is 81.87 J/g and the average particle size is about 50 nm with full wrap and uniform size.

关键词

羧甲基纤维素/蜜胺树脂/球形/相变胶囊/纳米材料

Key words

carboxymethyl cellulose/melamine resin/phase change microcapsule/nano material

分类

农业科技

引用本文复制引用

胡晓峰,黄占华..羧甲基纤维素/蜜胺树脂相变纳米储能材料的制备与表征[J].森林工程,2012,28(4):61-64,76,5.

基金项目

基金项目:国家自然科学基金项目 ()

中央高校专项基金项目 ()

教育部博士点新教师基金项目 ()

黑龙江省自然科学基金项目 ()

东北林业大学研究生科技创新项目 ()

森林工程

OACSTPCD

1006-8023

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